이범연 Bum-yeon Lee , 이창희 Chang-hee Lee

DOI:10.15681/KSWE.2021.37.6.425 Vol.37(No.6) 425-432, 2021

A tidal power plant (TPP) has been in operation since the end of 2011 to improve the water quality of Shihwa Coastal Reservoir (SCR). Tidal mixing rate increased 5.6 times after the TPP operation so that in this study, its effects on water quality was assessed through statistical analysis of long-term water quality monitoring data. It was found that the increased tidal mixing contributed to solving the hypoxia problem in the bottom water by preventing the summer stratification. The analysis also showed that the increased tidal mixing had different effects depending on the relative concentration difference for each water quality substances between the SCR and the outside of SCR. The average concentrations of some substances (chemical oxygen demand, total phosphorus, chlorophyll-a) with higher concentrations than the outside of SCR decreased due to the dilution effect, but the other substances (total nitrogen, dissolved inorganic nitrogen, dissolved inorganic phosphorus) with lower concentrations compared to the outside ones increased on the contrary. Factor analysis also showed a consistent result that the first factor accounting for the water quality was changed from the organic-related substances to the nutrient-related substances after the increased tidal mixing. These results imply that the focus of future water quality management needs shifting from the organic substances to the nutrients, particularly dissolved inorganic nutrients. Considering the effect of inflow seawater on the nutrients, the management area should be extended to cover not only SCR but also a certain area outside of SCR.

Restoration management, Shihwa coastal reservoir, Tidal mixing, Tidal power plant, Water quality, Water quality assessment

이종훈 Jonghun Lee , 노호정 Hojung Rho , 박광덕 Kwang Duck Park , 우윤철 Yun Chul Woo

DOI:10.15681/KSWE.2021.37.6.433 Vol.37(No.6) 433-441, 2021

The aim of this study was to optimize the ozonation and ceramic membrane integrated process for greywater reclamation. The integrated process is a repeated sequential process of filtration and backwash with the same ceramic membrane. Also, this study used ozone and oxygen gas for the backwashing process to compare backwashing efficiency. The study results revealed that the optimum filtration and backwash time for the process was 10 minutes each when comparing the filtrate flow and membrane recovery rate. The integrated process was operated at three different operating conditions with i) 10 minutes for filtration and 10 minutes for ozonation, ii) 10 minutes for filtration and 10 minute for oxygen aeration, and iii) continuous filtration without any aeration for synthetic greywater. The integrated process with ozone backwashing could produce 0.55 L/min of filtrate with an average of 18.42% permeability recovery, while the oxygen backwashing produced 0.47 L/min and 6.26%, respectively. And without any backwashing, the integrated process could produce 0.29 L/min. This shows that the ozone backwash process is capable of periodically recovering from membrane fouling. The resistance of the fouled membrane was approximately 34.4% for the process with ozone backwashing, whereas the resistance was restored by 10.8% for the process with oxygen backwashing. Despite the periodical ozone backwashing and chemical cleaning, irreversible fouling gradually increased approximately 3 to 4%. Approximately 97.6% and 15% turbidity and TOC were removed by ceramic membrane filtration, respectively. Therefore, the integrated process with ozonation and ceramic membrane filtration is a potential greywater treatment process.

Advanced oxidation process, Ceramic membrane, Greywater treatment, Ozonation, Water treatment process

정상현 Sanghyun Jeong , David von Eiff , 변시영 Siyoung Byun , 이지은 Jieun Lee , Alicia Kyoungjin An

DOI:10.15681/KSWE.2021.37.6.442 Vol.37(No.6) 442-448, 2021

Seawater desalination is a technology through which salt and other constituents are removed from seawater to produce fresh water. While a significant amount of fresh water is produced, the desalination process is limited by the generation of concentrated brine with a higher salinity than seawater; this imposes environmental and economic problems. In this study, characteristics of seawater from three different locations in South Korea were analyzed to evaluate the feasibility of crystallization to seawater desalination. Organic and inorganic substances participating in crystal formation during concentration were identified. Then, prediction and economic feasibility analysis were conducted on the actual water flux and obtainable salt resources (i.e. Na2SO4) using membrane distillation and energy-saving crystallizer based on multi-stage flash (MSF-Cr). The seawater showed a rather low salinity (29.9~34.4 g/L) and different composition ratios depending on the location. At high concentrations, it was possible to observe the participation of dissolved organic matter and various ionic substances in crystalization. When crystallized, materials capable of forming various crystals are expected. However, it seems that different salt concentrations should be considered for each location. When the model developed using the Aspen Plus modular was applied in Korean seawater conditions, relatively high economic feasibility was confirmed in the MSF-Cr. The results of this study will help solve the environmental and economic problems of concentrated brine from seawater desalination.

Brine treatment, Crystallizer, Membrane distillation, Salt, Seawater desalination

허재희 Jae-Hee Huh , 심태석 Tae-suk Sim , 황선진 Sun-jin Hwang

DOI:10.15681/KSWE.2021.37.6.449 Vol.37(No.6) 449-457, 2021

Photosynthesis and respiration rate of microalgae are important factors during advanced wastewater treatment research using microalgae, There are several equipments and measurement methods for measuring photosynthesis and respiration, with different challenges that occur during pretreatment and stabilization of the analysis process. Therefore, in this study, for accurate Photosynthesis and Respiration (P&R) analyzer measurement, the analysis process was divided into pre-processing, DO stabilization, and analysis stages and each was optimized to enable accurate evaluation. For this purpose, the effect of DO saturation of the sample on P&R analysis, DO stabilization according to the degassing flow rate, and photoinhibition of the OD level on photosynthesis was investigated. Based on our study results, when DO was supersaturated, photosynthetic efficiency decreased due to photorespiration, making it inappropriate as a P&R sample. In addition, 0.5 L-N2/min level was the optimal nitrogen degassing flow rate for DO desaturation. The inhibition of photosynthetic efficiency by self-shading caused by the increase in OD was observed from OD 2.0, and it was found that P&R analysis is preferably performed on samples with OD less than 2.0. In addition, based on the above three optimization results , an optimized P&R Analyzer instruction for accurate P&R analysis was also presented.

Microalgae, Photosynthesis rate, Photorespiration, P&R analyzer, Respiration rate

정가영 Ka-Young Jung , 이윤경 Yun Kyung Lee , 유하영 HaYoung Yoo , 남귀숙 Gui-sook Nam , 허진 Jin Hur

DOI:10.15681/KSWE.2021.37.6.458 Vol.37(No.6) 458-468, 2021

In this study, we investigated the variations of dissolved organic matter (DOM) in an agricultural reservoir during the monsoon period (June to October, 2020) with respect to the organic carbon concentration (DOC), molecular weight distribution, and optical properties. The monsoon period was divided into three phases - beginning storm (BS), during storm (DS), and after storm (AS). Our results showed significant differences in the concentrations and characteristics of DOM during the summer monsoon. The DOC concentrations were decreased after the monsoon, probably due to a dilution effect. In contrast, increasing trends were observed in the specific UV absorbance (SUVA), and relative abundances of humic-like fluorescence and larger-sized compounds. These observations implied that the large-sized and humic-like organic components with terrestrial origins strongly affected the reservoir DOM after the summer monsoon. Meanwhile, biopolymer size fraction, which is associated with algal activity, became more abundant after the monsoon. These results suggest that DOM with autochthonous sources became dominant as a result of the inflow of nutrients into the reservoir after the storm. Spatial changes in DOM within the reservoir were not pronounced as much as the temporal variations. All taken, it can be concluded that the summer monsoon simply led to the decrease of DOM concentrations while the sources and the quality of DOM underwent substantial changes, which may enrich refractory organic matter in the reservoir. This study reveals the importance of in-depth DOM quality monitoring before and after summer monsoon for effective water quality management in agricultural reservoirs.

Dissolved organic matter, Fluorescence, Multivariate statistics, Size exclusion chromatography, Summer monsoon

김수홍 Soohong Kim , 홍지영 Jiyeong Hong , 박운지 Woonji Park , 김종건 Jonggun Kim , 임경재 Kyoungjae Lim

DOI:10.15681/KSWE.2021.37.6.469 Vol.37(No.6) 469-482, 2021

The recent climate change and urbanization have seen an increase in runoff and pollutant loads, and consequently significant negative water pollution. The characteristics of the pollutant loads vary among the different flow regime depending on their source and transport mechanism, However, pollutant load reduction based on flow regime perspectives has not been investigated thoroughly. Therefore, it is necessary to analyze the effects of concentration on pollutant load characteristics and reductions from each flow regime to develop efficient pollution management. As non-point pollutants continuously increase due to the increase in impervious area, efficient management is necessary. Therefore, in this study, 1) the characteristics of pollutant sources were analyzed at the Dalcheon Basin, 2) reduction of nonpoint pollution, and 3) reduction efficiency for flow regimes were analyzed. By analyzing the characteristics of the Dalcheon Basin, a reduction efficiency scenario for each pollutant source was constructed. The efficiency analysis showed 0.06% to 5.62% for the living scenario, 0.09 to 24.62% for the livestock scenario, 0.17% to 12.81% for the industry scenario, 9.45% to 38.45% for the land scenario, and 9.8% to 39.2% for the composite scenario. Therefore, various pollution reduction scenarios, taking into account the characteristics of pollutants and flow regime characteristics, can contribute to the development of efficient measurements to improve water quality at various flow regime perspectives in the Dalcheon Basin.

Flow regime, Non-point pollutant, Reduction efficiency, SWAT

이주원 Lee Juwon , 정은주 Jeong Eunju , 이정민 Lee Jungmin , 이용구 Lee Yong-Gu , 전강민 Chon Kangmin

DOI:10.15681/KSWE.2021.37.6.483 Vol.37(No.6) 483-492, 2021

This study evaluated the removal efficiencies of methylene blue (MB) and humic acids (HA) using a rice husk (RH) biochar and powdered activated carbon (PAC). The pseudo-second-order model better presented the adsorption of MB and HA onto a RH biochar than the pseudo-first-order model. Furthermore, better description of the adsorption behavior of MB and HA by the Langmuir isotherm model (R² of the RH biochar: MB = 0.986 and HA = 0.984; R² of PAC: MB = 0.997 and HA = 0.989) than the Freundlich isotherm model (R² of the RH biochar: MB = 0.955 and HA = 0.965; R² of PAC: MB = 0.982 and HA = 0.973) supports the assumption that monolayer adsorption played key roles in the removal of MB and HA using the RH biochar and PAC. Batch experiments were performed on the effects of dosage, temperature, and pH. For all experiments, PAC showed higher efficiencies than RH biochar and MB adsorption efficiencies were higher than those of HA. Adsorption efficiencies increased with increasing amounts of adsorbents and temperature. As the pH increased, adsorption efficiencies of MB were increased while adsorption efficiencies of HA were decreased.

Adsorption, Humic acids, Methylene blue, Powdered activated carbon, Rice husk biochar

이유현 Youhyun Lee , 김경민 Kyoung-min Kim

DOI:10.15681/KSWE.2021.37.6.493 Vol.37(No.6) 493-500, 2021

Floating solar photovoltaic (hereinafter PV) power generation is emerging as a proper alternative to overcome various environmental limitations of existing offshore PV generation. However, more government-led policy design and technical and institutional development are still required. Based on the policy agenda setting theory and technological innovation theory, this study contains the research questions concerning the co-evolution of technology and the floating solar PV policy. This study primarily evaluates the technological and institutional development level of floating solar PV policy through a survey of domestic floating solar PV experts. Secondly, we also analyze the kind of policy agenda that should be set a priori. Analyzing the priorities to be considered, the first environmental enhancement needs to be considered from both the technical and institutional aspects. The second candidate task for the policy agenda is residents’ conflict and improvement of regulations. Both candidate tasks need to be actively considered in the policy agenda from the institutional point of view. The third is publicity, profit sharing, follow-up monitoring, and cost. Among them, public relations and profit sharing are tasks that need to be considered in the policy agenda from the institutional point of view. On the other hand, the cost of follow-up monitoring should be considered as a policy agenda in terms of technology, system, and common aspects. Finally, there are technical standards. Likewise, technical standards need to be considered in the policy agenda in terms of both technical and institutional commonality.

Expert survey, Floating solar PV, Policy agenda, Renewable energy policy

이재엽 Lee Jai-yeop , 박새롬 Park Saerom , 김일호 Kim Ilho

DOI:10.15681/KSWE.2021.37.6.501 Vol.37(No.6) 501-509, 2021

In 2018, total 263 micro and emerging contaminants were selected as target substances by the Ministry of Environment, and 80 of them were first-class substance including endocrine disruptors, residual Pharmaceuticals and Personal Care Products (PPCPs), residual organic pollutants, pesticides and heavy metals. In this study, in order to evaluate the Hazard Quotient (HQ) of the 80 types in the domestic water environment the concentration of discharged effluent and nearby water environment reported by Korean institutes since 2010 was investigated. There were 45 substances reported to be detected, and Measurement Environment Concentration (MEC) were obtained by collectively converting them into water environment concentration. For biotoxicity, half maximal Effective Dose (EC50) to Daphnia magna, a water fleas species widely adopted in Material Safety Data Sheet (MSDS) was applied. As for the biotoxicity level, the Predicted No-Effect Concentration (PNEC) was obtained by applying the Assessment Factor (AF) and the HQ was derived by dividing it from the MEC. As a result of calculating the HQ, more than 1 substances were Cabamazepine, Mefenamic acid, Acetaminophen, Ibuprofen, Nonylphenol, Nickel, Erythromycin, Acetylslic acid, etc. Meanwhile, perfluorinated compounds were identified as hazardous substances in the water environment, with 5 out of 14 species included in the 20 ranks of first-class substance.

Emerging contaminants, Hazard quotient, Micropollutants, PNEC, Risk assessment

신명철 Myoung-chul Shin , 정다솜 Da-som Jung , 노혜란 Hye-ran Noh , 유순주 Soon-ju Yu , 서용찬 Yong-chan Seo , 이보미 Bo-mi Lee

DOI:10.15681/KSWE.2021.37.6.510 Vol.37(No.6) 510-519, 2021

Volatile Organic Compounds (VOCs) in sediments, which can cause human health problems, have been monitored in Korea since 2014. Measured VOC concentrations can be affected by matrix type and the volatility of target substances. In this study, (1) VOCs volatility and the influence of matrix interference were confirmed, and (2) internal standards (IS) method was applied to improve analytical method. For these purposes, method detection limit (MDL), calibration linearity, precision and accuracy of VOCs were compared in various matrices using the IS. Some of VOCs in sediments showed different peak areas and reduced rates compared to water matrix. It was suggested that adsorption properties of sediments hindered the migration to vapor during heat pretreatment in headspace method. A calibration curve was created in clean sand. Recovery rates for the calibration curve method and IS applying method were 64.1~83.1% and 99.1~119.3%, respectively. Relative standard deviations ranged from 11.1% to 21.6% for the calibration curve method and those for IS ranged 4.7% to 13.7%. In case of real sediment, calibration curve and 1,2-Dichlorobenzene-d4 (ODCB) among IS were not suitable. The average recovery rate of Fluorobenzene (FBZ) increased by 56.4% and Relative Standard Deviation (RSD) by 4.7%. However, the recovery rate was increased in the samples with large values of igniting intensity. This study confirmed that influence of the matrix of VOCs in sediment, and addition of IS materials improved precision and accuracy. Although IS corrects volatilization and adsorption, it is recommended that more than two types of IS should be added rather than single.

Headspace, Matrix Interference, Sediment, Volatile Organic Compounds

서영민 Seo Youngmin , 권구호 Kwon Kooho , 최윤영 Choi Yun Young , 이병준 Lee Byung Joon

DOI:10.15681/KSWE.2021.37.6.520 Vol.37(No.6) 520-530, 2021

Multivariate statistical analysis and an environmental hydrological model were applied for investigating the causes of water pollution and providing best management practices for water quality improvement in urban and agricultural watersheds. Principal component analysis (PCA) and cluster analysis (CA) for water quality time series data show that chemical oxygen demand (COD), total organic carbon (TOC), suspended solids (SS) and total phosphorus (T-P) are classified as non-point source pollutants that are highly correlated with river discharge. Total nitrogen (T-N), which has no correlation with river discharge and inverse relationship with water temperature, behaves like a point source with slow and consistent release. Biochemical oxygen demand (BOD) shows intermediate characteristics between point and non-point source pollutants. The results of the PCA and CA for the spatial water quality data indicate that the cluster 1 of the watersheds was characterized as upstream watersheds with good water quality and high proportion of forest. The cluster 3 shows however indicates the most polluted watersheds with substantial discharge of BOD and nutrients from urban sewage, agricultural and industrial activities. The cluster 2 shows intermediate characteristics between the clusters 1 and 3. The results of hydrological simulation program-Fortran (HSPF) model simulation indicated that the seasonal patterns of BOD, T-N and T-P are affected substantially by agricultural and livestock farming activities, untreated wastewater, and environmental flow. The spatial analysis on the model results indicates that the highly-populated watersheds are the prior contributors to the water quality degradation of the river.

Cluster analysis, Hydrological simulation program-fortran, Principal component analysis, Water quality

김진욱 Kim Jinuk , 장원진 Jang Wonjin , 신재기 Shin Jaeki , 강의태 Kang Euntae , 김진휘 Kim Jinhwi , 박용은 Park Yongeun , 김성준 Kim Seongjoon

DOI:10.15681/KSWE.2021.37.6.531 Vol.37(No.6) 531-538, 2021

In this study, the TOC in six estuarine reservoirs in the West Sea (Ganwol, Namyang, Daeho, Bunam, Sapkyo, and Asan) was estimated using optically-active water quality factors by the water environment monitoring network. First, specification data and land use maps of each estuarine reservoir were collected. Subsequently, water quality data from 2013 to 2020 were collected. The data comprised of 11 parameters: pH, dissolved oxygen, BOD, COD, suspended solids (SS), total nitrogen, total phosphorus, water temperature, electrical conductivity, total coliforms, and chlorophyll-a (Chl-a). The TOC in the estuarine reservoirs was 4.9~7.0 mg/L, with the highest TOC of 7.0 mg/L observed at the Namyang reservoir, which has a low shape coefficient and high drainage density. The correlation of TOC with water quality factors was also analyzed, and the correlation coefficients of Chl-a and SS were 0.28 and 0.19, respectively, while the correlation coefficients of these factors in the Namyang reservoir were 0.42 and 0.27, respectively. To improve the estimation of TOC using Chl-a and SS, the TOC was averaged in 5 mg/L units, and Chl-a and SS were averaged. Correlation analysis was then performed and the R² of Chl-a-TOC was 0.73. The R² of SS-TOC was 0.73 with a non-linear relationship. TOC had a significant non-linear relationship with Chl-a and SS. However, the relationship should be assessed in terms of the spatial and temporal variations to construct a reliable remote sensing system.

Data conversion, Estuarine reservoir, Optical properties, Total organic carbon, Water quality data